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Phys. Rev. E 81, 041502 (2010) [10 pages]

Glass transition of hard spheres in high dimensions

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Bernhard Schmid and Rolf Schilling
Institut für Physik, Johannes Gutenberg-Universität Mainz, Staudinger Weg 7, D-55099 Mainz, Germany

Received 22 December 2009; revised 14 February 2010; published 9 April 2010

We have investigated analytically and numerically the liquid-glass transition of hard spheres for dimensions d in the framework of mode-coupling theory. The numerical results for the critical collective and self-nonergodicity parameters fc(k;d) and fc(s)(k;d) exhibit non-Gaussian k dependence even up to d=800. fc(s)(k;d) and fc(k;d) differ for kd1/2, but become identical on a scale kd, which is proven analytically. The critical packing fraction φc(d)∼d22d is above the corresponding Kauzmann packing fraction φK(d) derived by a small cage expansion. Its quadratic pre-exponential factor is different from the linear one found earlier. The numerical values for the exponent parameter and therefore the critical exponents a and b depend on d, even for the largest values of d.

© 2010 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevE.81.041502
DOI:
10.1103/PhysRevE.81.041502
PACS:
64.70.P-, 64.70.Q-, 64.70.kj