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Phys. Rev. E 80, 021702 (2009) [8 pages]

Electroconvection in nematic mixtures of bent-core and calamitic molecules

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Shingo Tanaka and Hideo Takezoe
Department of Organic and Polymeric Materials, Tokyo Institute of Technology, 2-12-1 S8-Ookayama, Meguro-Ku, Tokyo 152-8552, Japan

Nándor Éber, Katalin Fodor-Csorba, Anikó Vajda, and Ágnes Buka
Research Institute for Solid State Physics and Optics, Hungarian Academy of Sciences, P.O. Box 49, H-1525 Budapest, Hungary

Received 16 April 2009; published 10 August 2009

The onset of electroconvection in binary mixtures of a bent-core and a rodlike nematic has been characterized by measuring the threshold voltage Uc and the critical wave number of the pattern in a wide range of frequencies f. In the mixtures rich in bent-core molecules, a “conductive-prewavy2-patternless-prewavy1” morphological sequence has been detected with an unusual negative slope of Uc(f) at high frequencies. This latter scenario seems to be related to the bent-core component, as it disappears with increasing the concentration of rodlike molecules. In addition, one of the parameters most relevant for electroconvection, the electrical conductivity, has also been varied by ionic salt doping. It has been found that the above effect of the banana-shaped molecules on the electroconvection scenarios can be suppressed by the conductivity.

© 2009 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevE.80.021702
DOI:
10.1103/PhysRevE.80.021702
PACS:
61.30.Gd, 47.54.−r, 47.20.Lz