Thermal convection in mixtures with an inversion of the separation ratio

We have numerically investigated Rayleigh-Bénard convection in binary mixtures assuming a thermal diffusion ratio that depends on the local temperature and changes its sign within the cell. The stationary instability has been found to precede the oscillatory one for a wide range of negative mean ψ values. The bifurcation diagram for stationary rolls turns out to be qualitatively different from that for constant Soret effect. Nevertheless, it can be mapped onto this special case by using a scaling argument, taking into account the fact that for small convection amplitudes the rolls are restricted to parts of the cell where the sign of the Soret coefficient favors instability.