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Phys. Rev. E 76, 051408 (2007) [5 pages]

Transition from a simple yield-stress fluid to a thixotropic material

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A. Ragouilliaux1,2, G. Ovarlez1, N. Shahidzadeh-Bonn1, Benjamin Herzhaft2, T. Palermo2, and P. Coussot1
1Université Paris-Est, Institut Navier, LMSGC, 2 Allée Kepler 77420 Champs, France
2IFP, 1-4 Avenue du Bois Préau, 92852 Rueil Malmaison, France

Received 13 June 2007; revised 7 September 2007; published 29 November 2007

From magnetic resonance imaging rheometry we show that a pure emulsion can be turned from a simple yield stress fluid to a thixotropic material by adding a small fraction of colloidal particles. The two fluids have the same behavior in the liquid regime but the loaded emulsion exhibits a critical shear rate below which no steady flows can be observed. For a stress below the yield stress, the pure emulsion abruptly stops flowing, whereas the viscosity of the loaded emulsion continuously increases in time, which leads to an apparent flow stoppage. This phenomenon can be very well represented by a model assuming a progressive increase of the number of droplet links via colloidal particles.

© 2007 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevE.76.051408
DOI:
10.1103/PhysRevE.76.051408
PACS:
82.70.−y, 61.43.Hv, 83.60.Pq