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Phys. Rev. E 72, 031110 (2005) [12 pages]

Exact effective transport dynamics in a one-dimensional random environment

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Marco Dentz*
Department of Geotechnical Engineering and Geosciences, Technical University of Catalonia (UPC), Barcelona, Spain

Brian Berkowitz
Department of Environmental Sciences and Energy Research, Weizmann Institute of Science, Rehovot, Israel

See Also: Erratum

Received 12 April 2005; revised 7 June 2005; published 28 September 2005

We study effective transport under linear equilibrium adsorption characterized by a spatially random retardation factor. In a stochastic framework, we present a methodology to quantify explicitly the impact of spatial disorder on effective transport dynamics. We derive an exact effective transport equation, which is equivalent to transport under linear kinetic adsorption characterized by a spectrum of adsorption times. The distribution of adsorption times is given explicitly in terms of the spatial disorder distribution. Furthermore, we find that effective transport is formally equivalent to a decoupled continuous time random walk. This observation and the explicit nature of the presented results allow for a mapping of the static disorder distribution on the transition time distribution.

© 2005 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevE.72.031110
DOI:
10.1103/PhysRevE.72.031110
PACS:
05.40.Fb, 05.60.−k, 02.50.−r

*Electronic address: marco.dentz@upc.es

Electronic address: brian.berkowitz@weizmann.ac.il

See Also

Erratum: Marco Dentz and Brian Berkowitz, Erratum: Exact effective transport dynamics in a one-dimensional random environment [Phys. Rev. E 72, 031110 (2005)], Phys. Rev. E 81, 059901 (2010).