corner
corner

Phys. Rev. E 71, 032501 (2005) [3 pages]

Does electrical double layer formation lead to salt exclusion or to uptake?

Download: PDF (39 kB) Buy this article Export: BibTeX or EndNote (RIS)

Johannes Lyklema
Laboratory of Physical Chemistry and Colloid Science, Wageningen University, Dreijenplein 6, 6703 HB Wageningen, The Netherlands

Received 1 October 2004; published 11 March 2005

When electric double layers are formed, cases have been reported where this formation involves expulsion of electrolyte into the solution and cases in which electrolyte is absorbed from the solution. Both situations are experimentally and theoretically documented, but they cannot be simultaneously correct. In this paper it is shown that this seeming conflict finds its cause in the way the double layer is formed: expulsion for double layers forming spontaneously by ion adsorption from the solution, but uptake when the double layer is formed by an external field. A thermodynamic analysis is presented.

© 2005 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevE.71.032501
DOI:
10.1103/PhysRevE.71.032501
PACS:
82.70.Dd