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Phys. Rev. E 66, 061301 (2002) [10 pages]

Thermodynamics and statistical mechanics of frozen systems in inherent states

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Annalisa Fierro, Mario Nicodemi*, and Antonio Coniglio
Dipartimento di Fisica, Università di Napoli “Federico II,” INFM, Unità di Napoli, Complesso Universitario Monte Sant’Angelo, Via Cinthia, I-80126 Napoli, Italy

Received 5 August 2002; published 10 December 2002

We discuss a statistical mechanics approach in the manner of Edwards to the “inherent states” (defined as the stable configurations in the potential energy landscape) of glassy systems and granular materials. We show that at stationarity the inherent states are distributed according a generalized Gibbs measure obtained assuming the validity of the principle of maximum entropy, under suitable constraints. In particular, we consider three lattice models (a diluted spin glass, a monodisperse hard-sphere system under gravity, and a hard-sphere binary mixture under gravity) undergoing a schematic “tap dynamics,” showing via Monte Carlo calculations that the time averages of macroscopic quantities over the tap dynamics and over such a generalized distribution coincide. We also discuss about the general validity of this approach to nonthermal systems.

© 2002 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevE.66.061301
DOI:
10.1103/PhysRevE.66.061301
PACS:
81.05.Rm, 05.20.-y, 75.10.Nr

*Also at Department of Mathematics, Imperial College, London, SW7 2BZ, U.K.