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Phys. Rev. E 63, 062701 (2001) [4 pages]

Observation of a pretransitional effect near a virtual smectic-A–smectic-C* transition

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Seiji Shibahara1, Yoichi Takanishi1, Jun Yamamoto2, Toyokazu Ogasawara1, Ken Ishikawa1, Hiroshi Yokoyama2, and Hideo Takezoe1
1Department of Organic and Polymeric Materials, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo 152-8552, Japan
2Japan Science and Technology Corporation, Tokodai, Tsukuba, Ibaraki 300-2635, Japan

Received 16 August 2000; published 15 May 2001

Unusual softening of the layer compression modulus B has been observed near the phase boundary where the smectic-C* phase vanishes in a naphtalene-based liquid crystal mixture. From the systematic study of x-ray and layer compression measurements, this unusual effect is attributed to the pretransitional softening near a virtual smectic-A–smectic-C* phase transition in the smectic-A phase, which no longer appears on the thermoequilibrium phase diagram. This phenomenon is similar but not equivalent to supercritical behavior.

© 2001 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevE.63.062701
DOI:
10.1103/PhysRevE.63.062701
PACS:
61.30.-v, 62.20.Dc, 64.70.Md